Analysis of Crystalline Phases of Electroactive Forms of Copolymer Composite of Polyvinylidene Fluoride and Tetrafluoroethylene with Nanographite

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Abstract

The influence of the crystallization conditions of vinylidene fluoride (VDF) copolymer with tetrafluoroethylene (TFE) (F-42) from aprotic solvents dimethyl sulfoxide (DMSO) and dimethylformamide (DMF) under isothermal conditions at 60, 90, 150°C on the phase composition of the films was studied. The content of crystalline phases in F-42 films was studied using Fourier infrared spectroscopy, Raman spectroscopy, and X-ray phase analysis. The effect of filling copolymer films with nanographite on crystallinity phases was investigated. Filling with nanographite changes the crystal structure of polymer piezoelectric films and their piezoelectric properties, forming high-content electroactive β- and γ-phases during crystallization from 5 wt% solutions of aprotic solvents. Some features of the analysis of the content of crystalline allotropic phases by the above methods were found. The total content of crystalline electroactive phases of the VDF/TFE copolymer during isothermal crystallization from DMSO and DMF was 96–98%, while the content of the β-phase was 75–80%.

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About the authors

V. I. Bachurin

Yaroslavl Branch of the Valiev Institute of Physics and Technology of the RAS

Author for correspondence.
Email: vibachurin@mail.ru
Russian Federation, Yaroslavl, 150067

N. G. Savinsky

Yaroslavl Branch of the Valiev Institute of Physics and Technology of the RAS

Email: vibachurin@mail.ru
Russian Federation, Yaroslavl, 150067

A. P. Khramov

Demidov Yaroslavl State University

Email: artem.khramov.99.99@mail.ru
Russian Federation, Yaroslavl, 150003

M. A. Smirnova

Yaroslavl Branch of the Valiev Institute of Physics and Technology of the RAS

Email: vibachurin@mail.ru
Russian Federation, Yaroslavl, 150067

R. V. Selyukov

Yaroslavl Branch of the Valiev Institute of Physics and Technology of the RAS

Email: vibachurin@mail.ru
Russian Federation, Yaroslavl, 150067

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Supplementary files

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2. Fig. 1. FT-IR spectra of F-42 samples crystallised at 60°C from solution: DMSO/F-42 (1); DMSO/F-42 (2); DMSO/F-42-nanographite (3); DMSO/F-42-nanographite (4).

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3. Fig. 2. CPC spectrum of F-42 powder.

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4. Fig. 3. CPC spectrum of F-42 film crystallised from 5 wt% F-42 in DMSO with the addition of 5 wt% nanographite at 60°C for 72 h after the spectral response separation procedure.

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5. Fig. 4. XRD spectrum of the underside of a sample film crystallised from 5 wt% F-42 filled with 5 wt% nanographite at 60 °C for 72 h from DMSO solution. Two D peaks (band around 1340 cm-1) and a G-band around 1570 cm-1 are observed in the spectrum.

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6. Fig. 5. SEM image of the surface of the F-42 film sample filled with 5 wt% nanographite.

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7. Fig. 6. Diffractogram of a sample of initial F-42 powder after the peak separation procedure.

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