Anisotropy of Thermal Expansion of Oxoborate Warwickite

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Abstract

In this paper, the transition metal oxoborate warwickite (Fe2+,Mg)Fe3+(BO3)O is studied for the first time by low- and high-temperature X-ray diffraction in the temperature range from 93 to 513 K. The sharply anisotropic nature of its thermal expansion is revealed. A structural interpretation of the expansion mechanism is given both in terms of the contribution of cationic and oxocentered polyhedra.

About the authors

Ya. P. Biryukov

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: y.p.biryukov@gmail.com
Россия, 199034, наб. Макарова, 2, Санкт-Петербург

R S. Bubnova

Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 199034, St. Petersburg, Russia

Email: rimma_bubnova@mail.ru
Россия, 199034, Санкт-Петербург, наб. Макарова, 2

S. K. Filatov

Saint Petersburg State University

Author for correspondence.
Email: filatov.stanislav@gmail.com
Russia, Saint Petersburg

References

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Copyright (c) 2023 Я.П. Бирюков, Р.С. Бубнова, С.К. Филатов