Convenient Preparation of tert-Butyl Amino Acid Esters from tert-Butanol

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A preparation of tert-butyl esters of amino acid is described that proceeds from protected amino acids and tert-butanol using anhydrous magnesium sulfate and an excess of boron trifluoride diethyl etherate as additional reagents. The method affords tert-butyl esters in good yields and a variety of amino acid side chains and substituents tolerate the reaction conditions.

Sobre autores

V. Azev

Branch of Shemyakin and Ovchinnikov Bioorganic Chemistry Institute RAS,

Autor responsável pela correspondência
Email: viatcheslav.azev@bibch.ru
Russia, 142290, Puschino, prosp. Nauki 6

A. Chulin

Branch of Shemyakin and Ovchinnikov Bioorganic Chemistry Institute RAS,

Email: viatcheslav.azev@bibch.ru
Russia, 142290, Puschino, prosp. Nauki 6

M. Molchanov

Istitute for Theoretical and Experimental Biophysics RAS

Email: viatcheslav.azev@bibch.ru
Russia, 142290, Puschino, Institutskaya ul. 3

A. Miroshnikov

Shemyakin–Ovchinnikov Institute of Bioorganic Chemistry RAS

Email: viatcheslav.azev@bibch.ru
Russia, 117997, Moscow, ul. Miklukho-Maklaya 16/10

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Declaração de direitos autorais © В.Н. Азев, А.Н. Чулин, М.В. Молчанов, А.И. Мирошников, 2023