Extraction of REE(III) with Mixtures of Picrolonic Acid and Bis-Carbamoylmethylphosphine Oxides

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It was found that the extraction of REE(III) from weakly acidic chloride solutions into an organic phase containing bis-carbamoylmethylphosphine oxides increases significantly in the presence of picrolonic acid. The stoichiometry of the extracted complexes was determined, the effect of the aqueous phase composition, the nature of the organic solvent and the structure of bis-CMPO on the efficiency of metal ion extraction into the organic phase was considered. The use of picrolonic acid as a chelating component of the extraction mixture leads to a significantly greater increase in the extraction of REE(III) compared to 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone.

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作者简介

Alexander Turanov

Osipyan Institute of Solid State Physics of the Russian Academy of Sciences

编辑信件的主要联系方式.
Email: karan@iptm.ru
ORCID iD: 0000-0002-5064-191X
俄罗斯联邦, Chernogolovka

Vasily Karandashev

Institute of Microelectronics Technology and High-Purity Materials of the Russian Academy of Sciences

Email: karan@iptm.ru
ORCID iD: 0000-0003-0684-272X
俄罗斯联邦, Chernogolovka

Zhanna Burmiy

Institute of Microelectronics Technology and High-Purity Materials of the Russian Academy of Sciences

Email: karan@iptm.ru
ORCID iD: 0000-0003-4195-9392
俄罗斯联邦, Chernogolovka

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2. Scheme 1.

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3. Fig. 1. Distribution coefficients of REE(III) during extraction from 0.1 mol/L HCl solutions by isomolar mixtures of compound 2 and picrolonic acid in dichloroethane. [2] + [HP] = 0.005 mol/l.

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4. Fig. 2. Distribution coefficients of REE(III) during extraction from 0.3 mol/L HCl solutions with solutions of a mixture of 0.002 mol/L compound 2 and 0.01 mol/L picrolonic acid in organic solvents.

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5. Fig. 3. Distribution coefficients of REE(III) during extraction from 0.25 mol/L HCl solutions with solutions of 0.0025 mol/L compounds 1-4 or 0.005 mol/L carbamoylmethylphosphinoxide 5 in dichloroethane containing 0.01 mol/L picrolonic acid.

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6. Fig. 4. Dependence of REE(III) distribution coefficients on the concentration of picrolonic acid in dichloroethane containing 0.0025 mol/L compound 2 during extraction from 0.25 mol/L HCl solutions.

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7. Fig. 5. Dependence of REE(III) distribution coefficients on the concentration of compound 2 in dichloroethane containing 0.01 mol/L picrolonic acid during extraction from 0.25 mol/L HCl solutions.

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8. Fig. 6. Dependence of REE(III) distribution coefficients on HCl concentration in the aqueous phase during extraction with solutions of a mixture of 0.0025 mol/L compound 2 and 0.01 mol/L picrolonic acid in dichloroethane.

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9. Fig. 7. Dependence of REE(III) distribution coefficients on the concentration of 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone (HPy) in dichloroethane containing 0.005 mol/L of compound 2 during extraction from solutions with pH = 2.0.

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10. Fig. 8. Dependence of REE(III) distribution coefficients on the concentration of compound 2 in dichloroethane containing 0.03 mol/L 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone during extraction from solutions with pH = 2.0.

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11. Fig. 9. Dependence of REE(III) distribution coefficients on pH of the aqueous phase during extraction with solutions of a mixture of 0.005 mol/L compound 2 and 0.03 mol/L 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone in dichloroethane.

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