Coordination compounds of rare-earth Nitrates with N,N-dimethylacetamide

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Resumo

Coordination compounds of rare-earth nitrates with N,N-dimethylacetamide (DMAA), [Sc(H2O)(DMAA)2(NO3)(μ-OH)2Sc(NO3)(DMAA)2(H2O)](NO3)2, [La(DMAA)4(NO3)3], [Ce(DMAA)5(NO3)2][Ce(DMAA)2(NO3)4] and [Ln(DMAA)3(NO3)3] (Ln = Pr, Nd, Sm–Lu, Y), have been synthesized. Using physicochemical analysis methods (elemental analysis, IR spectroscopy, XRD, XRD, TGA-DSC), the compositions and structural features were determined; thermal decomposition of the compounds was studied in a wide temperature range (50–900°C). Complexes [Ln(DMAA)3(NO3)3] form two isostructural series: crystals with Ln = Pr–Dy belong to the monoclinic symmetry, and with Ln = Ho–Lu, Y – to the orthorhombic symmetry. It is shown that the coordination compounds can be used as precursors for the production of nanoscale REE oxides (from 12 to 50 nm) with a specific surface area of 18–65 m2/g.

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Sobre autores

M. Polukhin

MIREA—Russian Technological University

Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow, 119571

I. Karavaev

MIREA—Russian Technological University

Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow, 119571

E. Savinkina

MIREA—Russian Technological University

Autor responsável pela correspondência
Email: savinkina@mirea.ru

Lomonosov Institute of Fine Chemical Technologies

Rússia, Moscow, 119571

G. Buzanov

Kurnakov Institute of General and Inorganic Chemistry

Email: savinkina@mirea.ru
Rússia, Moscow, 119991

A. Kubasov

Kurnakov Institute of General and Inorganic Chemistry

Email: savinkina@mirea.ru
Rússia, Moscow, 119991

M. Grigoriev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: savinkina@mirea.ru
Rússia, Moscow, 119071

E. Turyshev

Kurnakov Institute of General and Inorganic Chemistry

Email: savinkina@mirea.ru
Rússia, Moscow, 119991

Bibliografia

  1. Wang Q., Fan H., Xiao Y., Zhang Y. // J. Rare Earths. 2022. V. 40. № 11. P. 1668. https://doi.org/10.1016/j.jre.2021.09.003
  2. Bo Liu, Na L., Liping S. et al. // J. Alloys Compd. 2021. V. 870. № 25. P. 159397. https://doi.org/10.1016/j.jallcom.2021.159397
  3. Huang K., Goodenough J.B. // J. Alloys Compd. 2000. V. 303–304. № 24. P. 454. https://doi.org/10.1016/S0925-8388(00)00626-5
  4. Wang B., Li K., Lui J. et al. // Int. J. Hydrogen Energy. 2024. V. 61. № 3. P 216. https://doi.org/10.1016/j.ijhydene.2024.02.198
  5. Richard A.R., Fan M. // J. Rare Earths. 2018. V. 36. № 11. P. 11127. https://doi.org/10.1016/j.jre.2018.02.012
  6. Colussi S., de Leitenburg C., Dolcetti G., Trovarelli A. // J. Alloys Compd. 2004. V. 374. № 1–2. P. 387. https://doi.org/10.1016/j.jallcom.2003.11.028
  7. Gao W., Wen D., Ho J.C., Qu Y. // Mater. Today Chem. 2019. V. 12. P. 266. https://doi.org/10.1016/j.mtchem.2019.02.002
  8. Zhang R., Tu Z.A., Meng S. et al. // Rare Met. 2023. V. 42. P. 176. https://doi.org/10.1007/s12598-022-02136-5
  9. Ahmad I., Akhtar M.S., Ahmed E. et al. // Sep. Purif. Technol. 2020. V. 237. № 15. P. 116328. https://doi.org/10.1016/j.seppur.2019.116328
  10. Kang W., Ozgur D.O., Varma A. // ACS Appl. Nano Mater. 2018. V. 1. № 2. P. 675. https://doi.org/10.1021/acsanm.7b00154
  11. Bakkiyaraj R., Bharath G., Hashi R.K. et al. // RSC Adv. 2016. V. 6. № 56. P. 51238. https://doi.org/10.1039/C6RA00382F
  12. Gupta S.K., Sudarshan K., Kadam R.M. // Mater. Today Commun. 2021. V. 27. P. 102227. https://doi.org/10.1016/j.mtcomm.2021.102277
  13. Nagabhushana H., Nagabhushana B.M., Rudraswamy B. et al. // Spectrochim. Acta, Part A: Mol. Biomol. Spectrosc. 2012. V. 86. P. 8. https://doi.org/10.1016/j.saa.2011.05.072
  14. Priya R., Pandey O.P., Sanjay J.D. // Optics & Laser Technology. 2021. V. 135. P. 106663. https://doi.org/10.1016/j.optlastec.2020.106663
  15. Liu N., Zhang J., Duan Y. et al. // J. Eur. Ceram. Soc. 2020. V. 40. № 4. P. 1132. https://doi.org/10.1016/j.jeurceramsoc.2019.11.058
  16. Ram P., Goren A., Ferdov S. et al. // New J. Chem. 2016. V. 40. № 7. P. 6244. https://doi.org/10.1016/j.compositesb.2017.11.054
  17. Halefoglu Y.Z., Yuksel M., Derin H. et al. // Appl. Radiat. Isot. 2018. V. 142. P. 46. https://doi.org/10.1016/j.apradiso.2018.09.012
  18. Ding Y., Zhang P., Jiang Y. et al. // Solid State Ionics. 2007. V. 178. № 13–14. P. 967. https://doi.org/10.1016/j.ssi.2007.04.012
  19. Shinde R.S., Jaiswal R.S., Kadam S.L. et al. // Energy Technol. 2024. V. 12. № 9. P. 2400608. https://doi.org/10.1002/ente.202400608
  20. Kim D. // Nanomaterials. 2021. V. 11. № 3. P. 723. https://doi.org/10.3390/nano11030723
  21. Zybert M., Ronduda H., Raróg-Pilecka W. // Front. Energy Res. 2023. V. 11. P. 1248641. https://doi.org/10.3389/fenrg.2023.1248641
  22. Subash T.D. // Mater. Today Proceed. 2017. V. 4. № 2. Part B. P. 4302. https://doi.org/10.1016/j.matpr.2017.02.134
  23. Shiri H.M., Ehsani A. // Bull. Chem. Soc. Jpn. 2016. V. 89. № 10. P. 1201. https://doi.org/10.1246/bcsj.20160082
  24. Bellakki M.B., Prakash A.S., Shivakumara C. et al. // Bull. Mater Sci. 2006. V. 29. P. 339. https://doi.org/10.1007/BF02704133
  25. Shirzadi-Ahodashti M., Mortazavi-Derazkola S., Ebrahimzadeh M.A. // J. Mater. Res. Technol. 2023. V. 27. P. 1843. https://doi.org/10.1016/j.jmrt.2023.10.079
  26. Yang J., Chen H., Zhang J. et al. // Surf. Coat. Technol. 2011. V. 205. № 23–24. P. 5497. https://doi.org/10.1016/j.surfcoat.2011.06.020
  27. Xiao H., Li P., Jia F., Zhang L. // J. Phys. Chem. C. 2009. V. 113. № 50. P. 21034. https://doi.org/10.1021/jp905538k
  28. Kabir H., Nandyala S.H., Mahbubur Rahman M. et al. // Ceram. Int. 2019. V. 45. № 1. P. 424. https://doi.org/10.1016/j.ceramint.2018.09.183
  29. Yang J., Chen H., Zhang J. et al. // Surf. Coat. Technol. 2011. V. 205. № 23–24. P. 5497. https://doi.org/10.1016/j.surfcoat.2011.06.020
  30. Li N., Yanagisawa K. // J. Solid State Chem. 2008. V. 181. № 8. P. 1738. https://doi.org/10.1016/j.jssc.2008.03.031
  31. Yin S., Akita S., Shinozaki M. et al. // J. Mater Sci. 2008. V. 43. P. 2234. https://doi.org/10.1007/s10853-007-2070-3
  32. Levashov E.A., Mukasyan A.S., Rogachev A.S., Shtansky D.V. // Int. Mater. Rev. 2017. V. 62. № 4. P. 203. https://doi.org/10.1080/09506608.2016.1243291
  33. Gizowska M., Piątek M., Perkowski K. et al. // Nanomater. 2020. V. 10. № 5. P. 831. https://doi.org/10.3390/nano10050831
  34. Кузнецов И.В., Зобкова А.Ю., Каленова М.Ю. и др. // Тонкие химические технологии. 2024. Т. 19. № 2. С. 149.
  35. Krsmanovic R., Lebedev O.I., Speghini A. et al. // Nanotechnology. 2006. V. 17. № 11. P. 2805. https://doi.org/10.1088/0957-4484/17/11/013
  36. Krsmanović R., Antić Ž., Bártová B., Dramićanin M.D. // J. Alloys Compd. 2010. V. 505. № 1. P. 224. https://doi.org/10.1016/j.jallcom.2010.06.033
  37. Peng T., Yang H., Pu X. et al. // Mater. Lett. 2004. V. 58. № 3–4. P. 352. https://doi.org/10.1016/S0167-577X(03)00499-3
  38. Lakshminarasappa B.N., Jayaramaiah J.R., Nagabhushana B.M. // Powder Technol. 2012. V. 217. P. 7. https://doi.org/10.1016/j.powtec.2011.09.042
  39. Savinkina E.V, Karavaev I.A., Grigoriev M.S. еt al. // Inorg. Chim. Acta. 2022. V. 532. P. 120759. https://doi.org/10.1016/j.ica.2021.120759
  40. Shi S., Hossu M., Hallb R., Chen W. // J. Mater. Chem. 2012. V. 22. P. 23461. https://doi.org/10.1039/C2JM34950G
  41. Fu Z., Liu B. // Ceram. Int. 2016. V. 42. № 2. P. 2357. https://doi.org/10.1016/j.ceramint.2015.10.032
  42. Moothedan M., Sherly K.B. // J. Water Process. 2016. V. 9. P. 29. https://doi.org/10.1016/j.jwpe.2015.11.002
  43. Mukherjee S., Sudarsan V., Sastry P.U. et al. // J. Lumin. 2014. V. 145. P. 318. https://doi.org/10.1016/j.jlumin.2013.07.058
  44. Chandradass J., Kim K.H. // Adv. Powder Techol. 2010. V. 21. № 2. P. 100. https://doi.org/10.1016/j.apt.2009.10.014
  45. Xia G., Wang S., Zhou S., Xu J. // Nanotechnology. 2010. V. 21. P. 345601. https://doi.org/ 10.1088/0957-4484/21/34/345601
  46. Петричко М.И., Караваев И.А., Савинкина Е.В. и др. // Журн. неорган. химии. 2023. Т. 68. № 4. С. 482.
  47. Ryskaliyeva A.K., Baltbayev M.E., Zhubatova A.M. // Acta Chim. Slov. 2018. V. 65. P. 127. https://doi.org/10.17344/acsi.2017.3683
  48. Vicentini G., De Carvalho Filho E. // J. Inorg. Nucl. Chem. 1966. V. 28. P. 2987. https://doi.org/10.1016/0022-1902(66)80026-X
  49. Matheus M., Briansó J.L., Solans X. et al. // Z. Kristallogr. Cryst. Mater. 1983. V. 165. № 1–4. P. 233. https://doi.org/10.1524/zkri.1983.165.14.233
  50. Rogers R.D. CCDC 1588497: Experimental Crystal Structure Determination, 2017. https://doi.org/10.5517/ccdc.csd.cc1q9yvt
  51. SAINT, Madison: Bruker AXS Inc., 2018.
  52. Krause L., Herbst-Irmer R., Sheldrick G.M., Stalke D. // J. Appl. Crystallogr. 2015. V. 48. № 1. P. 3. https://doi.org/10.1107/S1600576714022985
  53. Sheldrick G.M. SADABS. Madison, Wisconsin (USA): Bruker AXS, 2008.
  54. Sheldrick G.M. // Acta Crystallogr., Sect. A. 2008. V. 64. № 1. P. 112. https://doi.org/10.1107/S0108767307043930
  55. Sheldrick G.M. // Acta Crystallogr., Sect. C. 2015. V. 714. № 1. P. 3. https://doi.org/10.1107/S2053273314026370
  56. Allen F.H. Crystal Structure Visualisation, Exploration and Analysis software. Version 4.2.0. Cambridge Structural Database. 2019. https://doi.org/10.1017/S0885715619000666
  57. Караваев И.А., Савинкина Е.В., Григорьев М.С. // Журн. неорган. химии. 2022. Т. 67. № 8. С. 1080.
  58. Guan X.S., Dong Z.F., Li D.Y. // Nanotechnology. 2005. V. 16. P. 2963. https://doi.org/10.1088/0957-4484/16/12/040
  59. Birks L.S., Friedman H. // J. Appl. Phys. 1946. V. 17. P. 687. https://doi.org/10.1063/1.1707771

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2. Fig. 1. Structural series of synthesized complexes.

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3. Fig. 2. Experimental (a) and theoretical (b) diffraction patterns of the samples [Sc(H2O(DMAA)2(NO3)(μ-OH)2Sc(NO3)(DMAA)2(H2O)](NO3)2 (1), [La(DMAA)4(NO3)3] (2), [Ce(DMAA)5(NO3)2][Ce(DMAA)2(NO3)4] (3), [Eu(DMAA)3(NO3)3](monocle) (4) and [Er(DMAA)3(NO3)3](diamond) (5).

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4. Fig. 3. ORTEP view of coordination compounds I (a), II (b), III (c), VII (d), XII (d), hydrogen atoms are not shown.

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5. Fig. 4. Thermograms of the complexes [Pr(DMAA)3(NO3)3] (a) and [Eu(DMAA)3(NO3)3] (b); 1 – mass loss curve, 2 – differential curve.

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6. Fig. 5. Powder diffraction patterns of Pr6O11 (1), Eu2O3 (2), Ho2O3 (3), Er2O3 (4) and Y2O3 (5).

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7. Fig. 6. Micrographs of oxides Nd2O3 (a), Eu2O3 (b), Tb4O7 (c), Er2O3 (d).

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8. Fig. 7. Isotherms of N2 adsorption and desorption on the surface of La2O3 (a) and CeO2 (b).

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9. Fig. S1. IR spectra of the complexes: (a) – [Ln(DMAA)3(NO3)3] (monocle): Ln = Gd (1), Eu (2), Dy (3), Tb (4), Sm (5), Nd (6), Pr (7); (b) – [Ln’(DMAA)3(NO3)3] (diamond): Ln’ = Lu (1), Er (2), Ho (3), Yb (4), Y (5), Tm (6); (c): [Ce(DMAA)5(NO3)2][Ce(DMAA)2(NO3)4] (1), [Sc(H2O)(DMAA)2(NO3)(μ-OH)2(NO3)(DMAA)2(H2O)Sc](NO3)2 (2), [La(DMAA)3.7(NO3)3] (3)

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10. Fig. S2. Thermograms of the complexes: (a) – [La(DMAA)4(NO3)3], (b) – [Ce(DMAA)5(NO3)2][Ce(DMAA)2(NO3)4], (c) – [Nd(DMAA)3(NO3)3], (d) – [Y(DMAA)3(NO3)3], (e) – [Ho(DMAA)3(NO3)3], (f) – [Er(DMAA)3(NO3)3], (g) – [Tb(DMAA)3(NO3)3]: a – mass loss curve, b – differential curve

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11. Figure S3. IR spectrum of products of VII thermolysis at 315°C

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12. Supplementary materials
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13. Supplementary materials
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