Zinc(II) Chelate Complexes with Redox-Active o-Indophenols: Synthesis and Structure

封面

如何引用文章

全文:

开放存取 开放存取
受限制的访问 ##reader.subscriptionAccessGranted##
受限制的访问 订阅存取

详细

Zinc(II) complexes 2, 3, and 5 with redox-amphoteric o-indophenol ligands were prepared. The molecular structures of tetracoordinate complex 2 and hexacoordinate complex 3 were determined by single-crystal X-ray diffraction. The antioxidant properties of indophenols and their complexes were studied by cyclic voltammetry (CVA) and EPR spectroscopy. Complexation of indophenols increases the oxidation potentials by more than 0.84 V and leads to the formation of stable metal-containing radicals.

作者简介

E. Ivakhnenko

Institute of Physical and Inorganic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru
344091, Rostov-on-Don, Russia

Yu. Vitkovskaya

Institute of Physical and Inorganic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru
344091, Rostov-on-Don, Russia

K. Lysenko

Moscow State University

Email: ivakhnenko@sfedu.ru
119991, Moscow, Russia

S. Kislitsyn

Institute of Physical and Inorganic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru
344091, Rostov-on-Don, Russia

A. Starikov

Institute of Physical and Inorganic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru
344090, Rostov-on-Don, Russia

P. Knyazev

Institute of Physical and Inorganic Chemistry, Southern Federal University

Email: ivakhnenko@sfedu.ru
344090, Rostov-on-Don, Russia

A. Tereshchenko

International Institute for Smart Materials, Southern Federal University

Email: ivakhnenko@sfedu.ru
344090, Rostov-on-Don, Russia

V. Minkin

Institute of Physical and Inorganic Chemistry, Southern Federal University

编辑信件的主要联系方式.
Email: ivakhnenko@sfedu.ru
344091, Rostov-on-Don, Russia

参考

  1. Любченко С.Н., Литвинов В.В., Рыскина Т.А. и др. // Журн. общ. химии. 1990. Т. 60. № 7. С. 1618.
  2. Olekhnovich L.P., Ivakhnenko E.P., Lyubchenko S.N. et al. // Rossijskij Khimicheskij Zhurnal (Zhurnal Rossijskogo Khimicheskogo Obshchestva Im. D.I. Mendeleeva). 2004. V. 48. № 1. P. 103.
  3. Erickson A.N., Brown S.N. // Dalton Trans. 2018. V. 47. P. 15583. https://doi.org/10.1039/C8DT03392G
  4. Bally T. // Nat. Chem. 2010. V. 2. P. 165. https://doi.org/10.1038/nchem.564
  5. Sheldrick G.M. // Acta Crystallogr., Sect A. 2008. V. 64. P. 112. https://doi.org/10.1107/S0108767307043930
  6. Frisch M.J., Trucks G.W., Schlegel H.B. et al. // Gaussian 16 (Revision A.03), Gaussian, Inc., Wallingford (CT), 2016.
  7. Kohn W., Sham L.J. // Phys. Rev. 1965. V. 140. P. A1133. https://doi.org/10.1103/PhysRev.140.A1133
  8. Becke A.D. // J. Chem. Phys. 1993. V. 98. P. 5648. https://doi.org/10.1063/1.464913
  9. Chegerev M.G., Starikova A.A., Starikov A.G. et al. // Mendeleev Commun. 2022. V. 32. № 1. P. 49. https://doi.org/10.1016/j.mencom.2022.01.015
  10. Noodleman L. // J. Chem. Phys. 1981. V. 74. P. 5737. https://doi.org/10.1063/1.440939
  11. Shoji M., Koizumi K., Kitagawa Y. et al. // Chem. Phys. Lett. 2006. V. 432. P. 343. https://doi.org/10.1016/j.cplett.2006.10.023
  12. Chemcraft, version 1.8, 2014: http://www.chemcraftprog.com
  13. Ley K., Müller E. // Chem. Ber. 1956. V. 89. P. 1402. https://doi.org/10.1002/cber.19560890607
  14. Любченко С.Н., Ивахненко Е.П., Рыскина Т.А. и др. // Журн. общ. химии. 1989. Т. 59. № 5. С. 1104.
  15. Evangelio E., Ruiz-Molina D. // Eur. J. Inorg. Chem. 2005. № 15. P. 2957. https://doi.org/10.1002/ejic.200500323
  16. Tezgerevska T., Alley K.G., Boskovic C. // Coord. Chem. Rev. 2014. V. 268. P. 23. https://doi.org/10.1016/j.ccr.2014.01.014
  17. Minkin V.I., Starikov A.G. // Russ. Chem. Bull. 2015. V. 64. P. 475. https://doi.org/10.1007/s11172-015-0891-9
  18. Ershova I.V., Piskunov A.V., Cherkasov V.K. // Russ. Chem. Rev. 2020. V. 89. № 11. P. 1157. https://doi.org/10.1070/RCR4957
  19. Ovcharenko V.I., Kuznetsova O.V. // Russ. Chem. Rev. 2020. V. 89. № 11. P. 1261. https://doi.org/10.1070/RCR4981
  20. Fedushkin I.L., Maslova O.V., Baranov E.V. et al. // Inorg. Chem. 2009. V. 48. № 6. P. 2355. https://doi.org/10.1021/ic900022s
  21. Fedushkin I., Maslova O., Morozov A. et al. // Angew. Chem., Int. Ed. 2012. V. 51. № 42. P. 10584. https://doi.org/10.1002/anie.201204452
  22. Chegerev M.G., Starikova A.A., Piskunov A.V. et al. // Eur. J. Inorg. Chem. 2016. № 2. P. 252. https://doi.org/10.1002/ejic.201501155
  23. Chegerev M.G., Piskunov A.V., Starikova A.A. et al. // Eur. J. Inorg. Chem. 2018. № 9. P. 1087. https:// https://doi.org/10.1002/ejic.201701361
  24. Chegerev M.G., Piskunov A.V. // Russ. J. Coord. Chem. 2018. V. 44. № 4. P. 258. https://doi.org/10.1134/S1070328418040036
  25. Chaudhuri P., Hess M., Hildenbrand K. et al. // Inorg. Chem. 1999. V. 38. № 12. P. 2781. https://doi.org/10.1021/ic990003g
  26. Starikov A.G., Minkin V.I., Minyaev R.M. et al. // J. Phys. Chem. A. 2010. V. 114. № 29. P. 7780. https://doi.org/10.1021/jp101353m
  27. Coppinger G.M. // Tetrahedron. 1962. V. 18. P. 61. https://doi.org/10.1016/0040-4020(62)80024-6
  28. Ivakhnenko E.P. // Zh. Org. Khim. 1983. V. 19. № 4. P. 886.
  29. Prokof'ev A.I., Solodovnikov S.P., Nikiforov G.A. et al. // Russ. Chem. Bull. 1971. V. 2. P. 324.
  30. Ivakhnenko E.P., Knyazev P.A., Vitkovskaya Yu.G. et al. // Eur. J. Inorg. Chem. 2021. № 21. P. 2055. https://doi.org/10.1002/ejic.202100184

补充文件

附件文件
动作
1. JATS XML
下载
2.

下载 (394KB)
索引源数据
3.

下载 (401KB)
索引源数据
4.

下载 (72KB)
索引源数据
5.

下载 (43KB)
索引源数据
6.

下载 (47KB)
索引源数据
7.

下载 (352KB)
索引源数据
8.

下载 (30KB)
索引源数据
9.

下载 (165KB)
索引源数据
10.

下载 (32KB)
索引源数据
11.

下载 (335KB)
索引源数据

版权所有 © Е.П. Ивахненко, Ю.Г. Витковская, К.А. Лысенко, С.Е. Кислицин, А.Г. Стариков, П.А. Князев, А.А. Терещенко, В.И. Минкин, 2023