


Vol 126, No 3 (2025)
ЭЛЕКТРИЧЕСКИЕ И МАГНИТНЫЕ СВОЙСТВА
Ferromagnetic resonance and antiresonance in a composite material with cobalt nanoparticles
Abstract
The frequency and field dependences of the wave transmission and reflection coefficients of a composite material with cobalt nanoparticles in an opal matrix were measured at frequencies of 26–38 GHz. The phenomena of ferromagnetic resonance and antiresonance have been experimentally studied. The theoretical calculation of the dependences of the transmission and reflection coefficients on the magnetic field is performed. The specificity of antiresonance in a composite material has been revealed. The importance of taking into account the interference of waves in the nanocomposite is indicated. The field dependence of the depth of penetration of microwaves into the composite is calculated. Formulas for calculating the antiresonance field in a composite material are obtained.



Approach to low-frequency magnetic field measurements using permalloy-based magnetoplasmonic crystal
Abstract
This paper demonstrates the use of a one-dimensional magnetoplasmonic crystal based on Ni80Fe20 permalloy as a sensitive probe of a magneto-optical sensor for low-frequency AC field measurements. The sensitivity of the sensor reaches 30 mOe when operating in the frequency range from 0.1 to 100 Hz. In the course of the work, an assessment was made of the applicability of the developed sensor for measuring magnetic fields of biological objects that were subjected to electrical stimulation.



Spin-pumping size effect
Abstract
The spatial distribution of magnetization oscillations of pure spin current induced in a thin layer of a non-magnetic conductor due to spin pumping is theoretically investigated. The influence of boundary conditions is studied. It is shown that if the oscillation frequency is lower than the spin relaxation frequency, the voltage at the surface of the conductor layer due to the inverse spin Hall effect is maximum when the layer thickness is close to the spin diffusion length.



Comparison between different techniques for obtaining anisotropic Nd–Fe–B hard magnetic powders by the HDDR process
Abstract
The method for obtaining anisotropic hard magnetic Nd2Fe14B powders by the process Hydrogenation–Disproportionation–Desorption–Recombination (HDDR process) Nd–Fe–B type alloy with high content of Nd has been considered in this study. Two different types of HDDR (dynamic and solid) process have been studied. The dependence of magnetic hysteresis properties on hydrogen pressure and its pumping rate at the disproportionation stage is shown. It is found that a solid HDDR makes it possible to obtain powders with higher coercivity and the hysteresis loop rectangularity than a dynamic HDDR.



Control of magnetoelastic properties of Fe−Ga alloys using thermomechanical treatment
Abstract
The effect of thermomechanical treatment (TMechT), which includes annealing and cooling of the alloy under the external compressive load along the direction <001>, to magnetostriction of the Fe−18 at.%Ga alloy, has been investigated. Field dependencies of the longitudinal and transverse magnetostriction are measured after TMechT with compressing stresses of 0–8 MPa. It is shown that as a result of TMechT already with small compressive stresses ~1 MPa, a significant change in the magnetostrictive behavior of the monocrystalline alloy occurs. The longitudinal component of magnetostriction increases, and the transverse (by module) is reduced, while the complete magnetostrition practically does not change. The maximum value of the saturation magnetostriction is observed after TMechT under stress of 2 MPa − about 280 ppm. After TMechT at higher stresses it is at the level of 200 ppm, and decreases and reaches zero at 6 MPa. The observed effects of TMechO are explained by the directional ordering the Ga−Ga pairs in the BCC Fe−Ga alloy.



СТРУКТУРА, ФАЗОВЫЕ ПРЕВРАЩЕНИЯ И ДИФФУЗИЯ
Cluster structure of melts of metals with a densely packed structure
Abstract
A model of the cluster structure of metal melts with a densely packed structure is considered. The minimum cluster size in the melt at the melting temperature of the crystal is determined. Using a 3-atomic chain of particles (in the Frenkel solid state model) interacting with a paired Morse potential, it is possible to obtain an estimate of the parameter determining the energy of interaction of particles in the chain. The value obtained is less than the value corresponding to the critical point of the order–disorder phase transition for inter-cluster boundaries in a 2-dimensional system. It is found that the change in the energy of a 3-dimensional system as a function of its temperature has an inflection point at a value corresponding to the structural disorder of the system: the critical point of the order–disorder phase transition for a two-dimensional layer of boundary nodes.



Microstructure of hypereutectic silumin at high-speed solidification
Abstract
The paper presents the results of a study of the microstructure of Al–20.1Si–0.2Fe and Al–21.3Si–0.8Mg–0.5Fe–0.3Mn–0.6Ni–1.4Cu alloys (the concentration values of the elements are given in wt%) obtained by ultrafast quenching from the melt. It is shown that the foil has a two-layer microstructure, which is formed as a result of changing the solidification conditions. Silicon liquation across the foil thickness is detected, leading to a reduced silicon concentration in the foil layer adjacent to the crystallizer and its precipitation at the layer boundary. A mechanism for the formation of a layered microstructure based on the locally nonequilibrium theory of crystallization is proposed. The nonequilibrium distribution coefficient is calculated at high-speed solidification taking into account the dependence of the volume and surface diffusion rate of silicon in the Al–Si melt on the Si concentration. A satisfactory relationship between the calculation results and experimental data is shown. An explanation is given for the dome-shaped boundary of layers with different microstructures based on an analysis of the morphology of the foil surface adjacent to the crystallizer.



Short-range order in soft magnetic alloy Fe–9 at.% Ga and conditions of its thermal treatment
Abstract
The atomic structure of monocrystalline samples of soft magnetic alloy Fe–9 at% Ga (A2-phase area) subjected to various thermal processing: 1 – quenching to water from paramagnetic state, 2 – annealing in a ferromagnetic state, 3 – thermomagnetic treatment (TMT) and 4 – thermomechanical treatment (TMechT), was studied by the method of X-ray diffraction. In the diffractograms of all samples, after different thermal treatments, diffuse peaks are observed, which are a contribution from small type of randomly located clusters of B2 type. A separate B2 cluster consists of a pair of BCC-cells centered by Ga atoms. The pair axis is parallel to one of the axes of easy magnetization <100>. It is shown that the width of diffuse peaks measured during scanning along the axis [001] decreases and, therefore, the average size of B2 clusters along this axis increases depending on the processing in the sequence of 1–2–3–4. The results obtained indicate a restructuring of short range order under the influence of TMT and TMechT.



Phase-field modeling of multiphase single-component system microstructure formation
Abstract
The present study employs a phase-field description to consider the crystallisation process of one-component systems with microstructure formation. A closed physical and mathematical model of thermodynamically consistent relaxation equations for phase fields and heat conduction equations describing the interaction of different phases and crystallites of one phase with each other is obtained. The model incorporates latent heat of phase transition and is derived from the principle of entropy increase and enthalpy conservation law. A method of introducing phase-field fluctuations is proposed, with the aim of simulating homogeneous nucleation in the melt. The investigation of edge angle formation at the contact of three phases is undertaken on the basis of the obtained model. The crystallite size distribution obtained from the model is then compared with the theoretical Hillert distribution. The study goes on to examine the dependence of crystallite shape and size distribution on thermal gradient, and the influence of thermodynamic conditions on the process of polymorphic δ–γ transformation.



ПРОЧНОСТЬ И ПЛАСТИЧНОСТЬ
Model of transient creep for a ferritic-martensitic steel based on the modified θ-projection method
Abstract
The paper presents the developed model for predicting the behavior of a ferritic-martensitic steel during all creep stages. A modified θ-projection method is proposed as a solution. The main advantages of the method are abilities to model creep curves for a wide range of temperatures and stresses (which reduces the need for long-term run tests); to validate calculations by determining time to failure; to predict a steady-state creep rate. Despite the usefulness of the proposed approach, certain limitations are noted that result in modeling uncertainties. Higher accuracy and robustness can be achieved using a "mechanical equation of state equation" model of Rabotnov type.



Nitriding of the iron-titanium phase: first-principles calculations based on experimental data
Abstract
A fundamental understanding of the effect of nitriding, which is used to improve the mechanical properties of surfaces, is required to control the effect of nitriding. Modern methods of quantum mechanical modelling make it possible to carry out cost-effective and reliable studies of the mechanisms of nitriding effects on surfaces. In this paper, the effect of nitriding on the structure and mechanical properties of titanised steel using the FeTi model is studied on the basis of density functional theory calculations. Two cases of nitrogen presence in the Fe–Ti crystal are considered: uniform distribution and nitrogen clustering. On the basis of calculations of the formation energy and analysis of the population of crystal Hamilton orbitals, it is found that higher stability of FeTi is achieved at low nitrogen concentrations up to 5.4% when nitrogen atoms are uniformly distributed, whereas in the case of nitrogen clustering FeTi is more stable at higher nitrogen concentrations from 3.7% to 7.4%. The mechanical properties of nitrogen-containing FeTi suggest that Young's modulus and shear modulus increase with increasing nitrogen concentration up to 5.4%. The results obtained not only provide fundamental knowledge about the effect of nitriding of titanised iron-based steels, but also provide new knowledge necessary for planning experimental studies.



Fine structure of pipe steel X70 after long-term operation
Abstract
The ferrite-bainite structure of X70 grade pipe steel was analyzed using transmission electron microscopy. The steel was produced using thermomechanical controlled processing technology and was used as part of a main gas pipeline for 40 years. It was shown, that during operation deformation aging processes develop in the steel structure, which significantly change the state of the fine structure of each of the phase components.


