Activation of Phenyl-N-(triflyl)imino-λ3-iodane by Metal Salts in Reactions with Alkenes

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The reactions of alkenes with phenyl-N-(triflyl)imino-λ3-iodane PhI=NTf 1 under different conditions were studied. Optimization of the reaction conditions of 1 with styrenes in the presence of copper (I) chloride leads to aziridine and bis(triflamidation) products in different ratios. The use, in the same reaction, of silver nitrate as a catalyzing additive leads to 1-phenyl-2-(triflamido)ethyl nitrate. Involvement of camphene as substrate and varying the catalyzing additive under oxidizing conditions can lead to isomeric acetamidines. The possible biological activity for the obtained compounds was evaluated.

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作者简介

A. Ganin

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

编辑信件的主要联系方式.
Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-1626-795X
俄罗斯联邦, ul. Favorskogo, 1, Irkutsk, 664033

I. Garagan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: ganin@irioch.irk.ru
ORCID iD: 0000-0003-3024-798X
俄罗斯联邦, ul. Favorskogo, 1, Irkutsk, 664033

M. Sobyanina

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: ganin@irioch.irk.ru
ORCID iD: 0000-0002-0361-0897
俄罗斯联邦, ul. Favorskogo, 1, Irkutsk, 664033

M. Moskalik

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

Email: ganin@irioch.irk.ru
俄罗斯联邦, ul. Favorskogo, 1, Irkutsk, 664033

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