电邮这篇文章 Chemical transformations of fatty acids in the hydrolysis of triglycerides. selective isolation of oleic acid from rapeseed oil under sub- and supercritical water conditions
- 作者: Aetov A.U.1, Usmanov R.A.1, Gabitov R.R.1, Mazanov S.V.1, Vol’eva V.B.2, Ryzhakova A.V.2, Musin R.Z.3, Gumerov F.M.1, Varfolomeev S.D.2
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隶属关系:
- Kazan National Research Technological University
- N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences
- A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
- 期: 卷 60, 编号 4 (2024)
- 页面: 486-494
- 栏目: Articles
- URL: https://archivog.com/0514-7492/article/view/672169
- DOI: https://doi.org/10.31857/S0514749224040098
- EDN: https://elibrary.ru/RYXXXI
- ID: 672169
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详细
The hydrolysis of rapeseed oil in sub- and supercritical water (T = 573–653 K, p = 30 MPa) has been studied using a batch setup. Unlike traditional hydrolysis, the hydrothermal process involves in situ change of the fatty acid composition as a result of the transformation of linoleic acid to oleic acid, and there is the possibility of selective isolation of the latter with a purity sufficient for its use for technical purposes without special purification. A stepwise mechanism of the hydrothermal process has been proposed on the basis of analysis of transformation products of individual linoleic acid.
作者简介
A. Aetov
Kazan National Research Technological University
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0002-9371-332X
俄罗斯联邦, ul. Karla Marksa, 68, Kazan, 420015
R. Usmanov
Kazan National Research Technological University
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0001-7007-0328
俄罗斯联邦, ul. Karla Marksa, 68, Kazan, 420015
R. Gabitov
Kazan National Research Technological University
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0003-4873-8496
俄罗斯联邦, ul. Karla Marksa, 68, Kazan, 420015
S. Mazanov
Kazan National Research Technological University
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0002-1718-5262
俄罗斯联邦, ul. Karla Marksa, 68, Kazan, 420015
V. Vol’eva
N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences
编辑信件的主要联系方式.
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0002-7034-7486
俄罗斯联邦, ul. Kosygina, 4, Moscow, 119334
A. Ryzhakova
N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0002-5063-0065
俄罗斯联邦, ul. Kosygina, 4, Moscow, 119334
R. Musin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0003-4526-4221
俄罗斯联邦, ul. Arbuzova, 8, Kazan, 420088
F. Gumerov
Kazan National Research Technological University
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0002-3806-2165
俄罗斯联邦, ul. Karla Marksa, 68, Kazan, 420015
S. Varfolomeev
N. M. Emanuel Institute of Biochemical Physics of Russian Academy of Sciences
Email: violetta.voleva@gmail.com
ORCID iD: 0000-0003-2793-0710
俄罗斯联邦, ul. Kosygina, 4, Moscow, 119334
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