Влияние условий модификации окисленных углеродных нанотрубок на каталитическую активность и селективность в реакции восстановления кислорода до пероксида водорода

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Аннотация

Катализаторы катодного получения пероксида водорода из кислорода были получены из предварительно окисленных азотной кислотой многостенных углеродных нанотрубок (МУНТ) с последующим восстановлением водородом в диапазоне температур 300–500°С. Исследование физико-химических свойств материалов показало, что выбранный метод синтеза позволяет контролируемо изменять состав кислородных групп на поверхности с сохранением текстурных характеристик и морфологии нанотрубок. Исследование каталитической активности в катодном процессе получения пероксида водорода показало, что наибольшей эффективностью обладает образец, восстановленный при температуре 300°С, содержащий 5.2 ат. % кислорода по данным РФЭС. Образец позволяет получать пероксид водорода со скоростью 0.34 моль/(г·ч) и фарадеевской эффективностью 78%. Дальнейшее увеличение температуры восстановления приводит к снижению скорости накопления Н2О2 при сохраняющейся фарадеевской эффективности.

Об авторах

Н. В. Мальцева

Новосибирский государственный университет; Институт катализа им. Г.К. Борескова СО РАН

Автор, ответственный за переписку.
Email: maltseva.n.v@catalysis.ru
Россия, Новосибирск; Новосибирск

С. И. Мосеенков

Институт катализа им. Г.К. Борескова СО РАН

Email: maltseva.n.v@catalysis.ru
Россия, Новосибирск

М. В. Лебедева

Новосибирский государственный университет; Институт катализа им. Г.К. Борескова СО РАН

Email: maltseva.n.v@catalysis.ru
Россия, Новосибирск; Новосибирск

Д. В. Козлов

Новосибирский государственный университет; Институт катализа им. Г.К. Борескова СО РАН

Email: maltseva.n.v@catalysis.ru
Россия, Новосибирск; Новосибирск

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