Calcium silicate based material as a filler for paint coatings

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Paint coatings with optimal performance properties are an important element in the safety and efficiency of marine and river vessels, as well as other objects exploited in the aquatic environment. In this work for modification of paint and varnish coatings we used a material based on calcium hydrosilicate, obtained by hydrothermal method from technogenic waste in the form of borogypsum. The synthesis product with specific surface 155.2 m2/g and density 3.1 g/cm3 is characterized by the presence of phases of calcium sulfate, tobermorite and xonotlite and consists of mainly from needle particles. The influence of calcium hydrosilicate, partially replacing calcium carbonate, on the properties of paint coatings based on acrylic copolymer has been studied. Physical and mechanical properties, antifouling effect, water absorption and erosion rate of paint coatings were studied.The results of the study showed the efficiency of calcium silicate use to improve the physical and mechanical properties of coatings: an increase in strength by 1.5 times was found. At the same time, the addition of calcium hydrosilicate at partial replacement of calcium carbonate does not decrease the antifouling effect.

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S. Yarusova

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

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Email: yarusova_10@mail.ru
俄罗斯联邦, Vladivostok

U. Kharchenko

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

Email: yarusova_10@mail.ru
俄罗斯联邦, Vladivostok

P. Gordienko

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

Email: yarusova_10@mail.ru
俄罗斯联邦, Vladivostok

S. Danilova

North-Eastern Federal University M.K. Ammosova

Email: yarusova_10@mail.ru
俄罗斯联邦, Yakutsk

D. Nguyen

Primorsky branch of the Joint Russian-Vietnamese Tropical Research Center

Email: yarusova_10@mail.ru
越南, Khanh Hoa

I. Beleneva

National Scientific Center for Marine Biology, Far Eastern Branch of the Russian Academy of Sciences

Email: yarusova_10@mail.ru
俄罗斯联邦, Vladivostok

D. Shlyk

Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences

Email: yarusova_10@mail.ru
俄罗斯联邦, Vladivostok

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2. Fig. 1. Diffraction pattern of the precipitate obtained as a result of autoclave treatment of boric acid production waste at a temperature of 220°C for 6 hours.

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3. Fig. 2. SEM images of calcium silicate sample.

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4. Fig. 3. Thermogravigram of a SC sample dried at a temperature of 20°C.

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5. Fig. 4. Antifouling efficiency of coating samples with different fillers: control – unpainted plexiglass panel; antifouling coatings: coating 1 – with CaCO3 as a filler; coating 2 – with partial replacement of CaCO3 with calcium hydrosilicate; coating 3 – with complete replacement of CaCO3 with calcium hydrosilicate.

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6. Fig. 5. Water sorption and coating erosion rates with varying filler composition.

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